Double CO2 activation by 14-electron η(8)-permethylpentalene titanium dialkyl complexes.
نویسندگان
چکیده
The novel 14 electron species η(8)-Pn*TiR2 (Pn* = C8Me6; R = Me, CH2Ph) have been synthesised and spectroscopically and structurally characterised. Subsequent reaction with CO2 leads to the activation and double insertion of CO2 into both Ti-alkyl bonds to form the electronically saturated η(8)-Pn*Ti(κ(2)-O2CR)2 (R = Me, CH2Ph) complexes.
منابع مشابه
Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex.
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عنوان ژورنال:
- Chemical communications
دوره 51 59 شماره
صفحات -
تاریخ انتشار 2015